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NGHIÊN CỨU TỔNG HỢP VÀ TÍNH CHẤT CỦA MỘT SỐ HỢP CHẤT CHỨA VÒNG 2-PIRAZOLIN

Phạm Văn Hoan, Đỗ Thị Minh Phương, Hà Mạnh Hùng, Vũ Quốc Trung

Abstract


The reactions of some unsaturated a,b-ketones with hydrazines and some its derivatives were investigated. unsaturated a,b-ketones reacted with hydrazine derivatives RNHNH2 in acetic acid/sodium acetate to give 1-R-3,5-diaryl-2-pyrazolines. The reaction of unsaturated a,b-ketones with hydrazine, however, gave 1-acetyl-3,5-diaryl-2-pyrazolines. The structure of the obtained compounds were confirmed by IR, UV, NMR spectra. Photoluminescence of some compounds were also investigated.


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