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BACKONE equation of state for Cis-1, 3, 3, 3-tetrafluoropropene (R1234ze(Z))

Phan Thi Thu Huong, Lai Ngoc Anh

Abstract


This paper presents the study on the determination of the thermodynamic properties of Cis-1,3,3,3-tetrafluoropropene (R1234ze(Z)) with the BACKONE equation of state. The BACKONE's characteristic temperature T0, characteristic density ρ0, anisotropy factor α, and reduce quarupole moment Q*2 were found by fitting the BACKONE EOS to experimental data of vapor pressure and saturated liquid density. All thermodynamic properties such as vapor pressure, pressure in gaseous phase, saturated liquid density, and liquid density can be determined easily from the found molecular characteristic properties. Thermodynamic properties of the R1234ze(Z) were evaluated with available experimental data. Average absolute deviations between calculated vapor pressure data and experimental data were 0.43%. Average absolute deviations between calculated saturated liquid density data and experimental data were 0.43%. In the prediction of the thermodynamic properties, average absolute deviations between calculated liquid density data and experimental data were 0.68% and average absolute deviations between calculated gas density data and experimental data were 1.6%.


Keywords


HFO-1234ze(Z); R1234ze(Z); thermodynamic properties; BACKONE equation of state (EOS)

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References


M. O. Mclinden, A. F. Kazakov, J. S. Brown, and P. A. Domanski. A thermodynamic analysis of refrigerants: Possibilities and tradeoffs for Low-GWP refrigerants. International Journal of Refrigeration, 38, (2014), pp. 80–92. https://doi.org/10.1016/j.ijrefrig.2013.09.032.

S. Fukuda, C. Kondou, N. Takata, and S. Koyama. Low GWP refrigerants R1234ze (E) and R1234ze (Z) for high temperature heat pumps. International journal of Refrigeration, 40, (2014), pp. 161–173. https://doi.org/10.1016/j.ijrefrig.2013.10.014.

C. Kondou and S. Koyama. Thermodynamic assessment of high-temperature heat pumps using Low-GWP HFO refrigerants for heat recovery. International Journal of Refrigeration, 53, (2015), pp. 126–141. https://doi.org/10.1016/j.ijrefrig.2014.09.018.

G. A. Longo, C. Zilio, G. Righetti, and J. S. Brown. Experimental assessment of the low GWP refrigerant HFO-1234ze (Z) for high temperature heat pumps. Experimental Thermal and Fluid Science, 57, (2014), pp. 293–300. https://doi.org/10.1016/j.expthermflusci.2014.05.004.

P. Petr and G. Raabe. Evaluation of R-1234ze (Z) as drop-in replacement for R-245fa in Organic Rankine Cycles–From thermophysical properties to cycle performance. Energy, 93, (2015), pp. 266–274. https://doi.org/10.1016/j.energy.2015.09.035.

J. S. Brown, C. Zilio, and A. Cavallini. The fluorinated olefin R-1234ze (Z) as a high-temperature heat pumping refrigerant. International Journal of Refrigeration, 32, (6), (2009), pp. 1412–1422. https://doi.org/10.1016/j.ijrefrig.2009.03.002.

S. Zhang, H. Wang, and T. Guo. Evaluation of non-azeotropic mixtures containing HFOs as potential refrigerants in refrigeration and high-temperature heat pump systems. Science China Technological Sciences, 53, (7), (2010), pp. 1855–1861. https://doi.org/10.1007/s11431-010-4008-2.

Y. Higashi, S. Hayasaka, C. Shirai, and R. Akasaka. Measurements of PρT properties, vapor pressures, saturated densities, and critical parameters for R 1234ze(Z) and R 245fa. International Journal of Refrigeration, 52, (2015), pp. 100–108. https://doi.org/10.1016/j.ijrefrig.2014.12.007.

L. Fedele, G. Di Nicola, J. S. Brown, S. Bobbo, and C. Zilio. Measurements and correlations of cis-1, 3, 3, 3-tetrafluoroprop-1-ene (R1234ze (Z)) saturation pressure. International Journal of Thermophysics, 35, (1), (2014), pp. 1–12. https://doi.org/10.1007/s10765-013-1553-5.

J. S. Brown, G. Di Nicola, L. Fedele, S. Bobbo, and C. Zilio. Saturated pressure measurements of 3, 3, 3-trifluoroprop-1-ene (R1243zf) for reduced temperatures ranging from 0.62 to 0.98. Fluid Phase Equilibria, 351, (2013), pp. 48–52. https://doi.org/10.1016/j.fluid.2012.09.036.

C. Kondou, R. Nagata, N. Nii, S. Koyama, and Y. Higashi. Surface tension of low GWP refrigerants R1243zf, R1234ze (Z), and R1233zd (E). International Journal of Refrigeration, 53, (2015), pp. 80–89. https://doi.org/10.1016/j.ijrefrig.2015.01.005.

T. Katsuyuki. Measurements of vapor pressure and saturated liquid density for HFO-1234ze(E) and HFO-1234ze(Z). Journal of Chemical & Engineering Data, 61, (mar, 2016), pp. 1645–1648. https://doi.org/10.1021/acs.jced.5b01039.

S. Lago, P. A. G. Albo, and J. S. Brown. Compressed liquid speed of sound measurements of cis-1, 3, 3, 3-tetrafluoroprop-1-ene (R1234ze (Z)). International Journal of Refrigeration, 65, (2016), pp. 55–59. https://doi.org/10.1016/j.ijrefrig.2016.02.003.

R. Akasaka, Y. Higashi, A. Miyara, and S. Koyama. A fundamental equation of state for cis-1, 3, 3, 3-tetrafluoropropene (R-1234ze (Z)). International Journal of Refrigeration, 44, (2014), pp. 168–176. https://doi.org/10.1016/j.ijrefrig.2013.12.018.

J. S. Brown, C. Zilio, and A. Cavallini. Thermodynamic properties of eight fluorinated olefins. International Journal of Refrigeration, 33, (2), (2010), pp. 235–241. https://doi.org/10.1016/j.ijrefrig.2009.04.005.

N. A. Lai. Equations of state for HFO-1234ze (E) and their application in the study on refrigeration cycle. International Journal of Refrigeration, 43, (2014), pp. 194–202. https://doi.org/10.1016/j.ijrefrig.2013.11.011.

N. A. Lai and T. T. H. Phan. Review of the BACKONE equation of state and its applications. Molecular Physics, 115, (9-12), (2017), pp. 1041–1050. https://doi.org/10.1080/00268976.2016.1218562.

L. Fedele, J. S. Brown, G. Di Nicola, S. Bobbo, and M. Scattolini. Measurements and correlations of cis-1333-Tetrafluoroprop-1-ene (R1234ze (Z)) subcooled liquid density and vapor-phase PvT. International Journal of Thermophysics, 35, (8), (2014), pp. 1415–1434. https://doi.org/10.1007/s10765-014-1730-1.




DOI: https://doi.org/10.15625/0866-7136/13207

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